The vibrational frequencies of forsterite Mg2SiO4: an all-electron ab initio study with the CRYSTAL code

The vibrational spectrum of Mg₂SiO₄ olivine was calculated at the Γ point by using the periodic ab initio CRYSTAL program. An all electron localized Gaussian-type basis set and the B3LYP Hamiltonian were employed. The full set of frequencies (35 IR active, 36 Raman active, 10 “silent” modes) was computed and compared to experimental data from different sources (four for IR and four for Raman). A generally good agreement is observed with experiment (the mean absolute difference ranging from 7 to 10 cm⁻¹ for the various sets), when some of the experimental frequencies, whose attribution is uncertain or appears to be affected by large errors, are not taken into account. A small number of observed peaks are not consistent with calculated frequencies, and a few theoretical peaks do not correspond to measured values. The implications are discussed in detail. The full set of modes are characterized using different tools, namely isotopic substitution, direct inspection of the eigenvectors and graphical representation, so as to obtain a consistent mode assignment.     

Evolution of stress fields in the Por’ya Guba dike field (Kandalaksha Gulf, White Sea)

The tectonic evolution of the Por’ya Guba segment of the White Sea Rift System began in the late Paleoproterozoic, i.e., soon after completion of the Svecofennian collision. The fracture system that controlled localization of the lamproite dike complex was formed under conditions of horizontal compression combined with shear. Subsequently, this system predetermined the location of a rift-graben segment that formed as a result of simple shear. The reactivation of the rift system in the Middle Paleozoic proceeded in two stages. The first stage, when strike-slip movements along previously formed faults predominated, resulted in formation of quartz-carbonate veins bearing base-metal mineralization. The veins that filled the shear fractures opened owing to local reorientation of the stress field. The second stage fitted the transtension conditions, and the Late Devonian alkaline ultramafic dikes of this stage introded into the already existing fracture system, which was oriented at a roughly right angle to the predominant stress orientation.     

A study of three massive star-forming regions in CS lines

We have mapped three star-forming regions (G265.14+1.45, G269.16?1.14, G291.27?0.71) in the CS(3–2) and C³⁴S(2–1) lines using the 15 m SEST telescope (Chile), and analyzed the relative positions of methanol and H₂O masers, IRAS sources, and emission maxima in the CS lines. In most cases, the maser positions are close to those of the IRAS sources. We compared the radial velocities of the maser sources and high-density CS cores, and estimated the CS column densities assuming LTE. The sizes, densities, and masses of the dense core are estimated; the masses obtained in the LTE approximation agree with the virial masses.     

Mineralogy and PT formation conditions of lead-zinc ore at the Dzhimidon deposit, north Ossetia

The mineralogy and PT formation conditions of the Dzhimidon Pb-Zn deposit in the Sadon ore district are considered. The deposit is localized in metamorphic rocks of the Buron Formation, which pertain to the pre-Jurassic basement (lower structural stage) and are cut through by Upper Paleozoic granitoids, and in the Lower Jurassic terrigenous sequence (upper structural stage). Orebodies as quartz-sulfide veins are mainly hosted in the metamorphic rocks. Galena, sphalerite, chalcopyrite, pyrite, pyrrhotite, and arsenopyrite are the most abundant sulfides, while quartz, carbonates, chlorite, sericite, and feldspar are gangue minerals. The bismuth mineralization identified at this deposit for the first time is represented by diverse phases of the Ag-Pb-Bi-S system. Five stages of the ore deposit formation are recognized: a premineral stage (quartz-feldspar), three ore-bearing stages (pyrite-arsenopyrite, pyrrhotite-chalcopyrite-sphalerite, and arsenopyrite-sphalerite-galena), and a postmineral stage (quartz-calcite); each stage comprises one or several mineral assemblages. The study of fluid inclusions in quartz, calcite, and sphalerite of the premineral, ore-forming, and postmineral stages has shown that the ore was deposited mainly from Na chloride solution with a salinity varying from >22 to <1.0 wt % NaCl equiv at a temperature from 460 to ～120°C and 430–290 bars pressure. The third stage was characterized by an abrupt increase in temperature and by the appearance of Mg(Fe,Ca) chloride solutions equally with Na chloride fluids, presumably owing to the emplacement of granite porphyry.     

台闽北部地区海岸阶地之对比

针对台湾海峡东岸台湾北部的海岸阶地进行调查研究，并与西岸福建东北部的海岸阶地进行分析比较；着重阐述台湾西北部4个海岸区域阶地的特性（阶序、分布、高度、崖差、构成等）及其变动情况（阶地抬升、变窄、延伸等）；通过推断形成年代、测算隆升速率等，探讨研究区域的海岸线变化与构造升降运动，结果发现：台湾岛的海阶变化不仅受到海平面变动的影响，尚受到区域性地壳隆升的控制；福建沿海地区受蓬莱造山运动的影响极小，海岸阶地的形成主要是受到数次海平面变化的影响；福建沿海的隆升速率由北向南逐渐减少，总体上低于海峡东岸台湾岛的隆升率（平均2mm／a）．该研究印证了：相对于台湾岛地区，福建沿海地区的地壳活动相对稳定，其海阶发育可能仅受到海平面变动的影响．’     

Radio and optical spectra of objects from three complete samples of radio sources

We present classifications, optical identifications, and radio spectra for 19 radio sources from three complete samples, with declinations 4°–6° (B1950, S _{3.9 GHz} > 200 mJy), 10°–12°30′ (J2000, S _{4.85 GHz} > 200 mJy), and 74°–75° (J2000, S _{4.85 GHz} > 100 mJy). We also present corresponding information for the radio source J0527+0331. The right ascensions are 0–24^h and the Galactic latitudes |b| > 15° for all the samples. Our observations were obtained with the 6 m telescope from the Special Astrophysical Observatory in the range 4000–9000 Å or 4000–7500 Å and the RATAN-600 radio telescope at frequencies in the range 0.97–21.7 GHz. We obtained flux densities for the radio sources and optical spectra for their optical counterparts. Nine objects were classified as quasars with redshifts from z = 1.029 to 3.212; nine objects are emission-line galaxies with redshifts from 0.172 to 0.546, and one is a galaxy with burstlike star formation at z = 0.156, and one is a BL Lac object with z = 0.509. The spectra of five radio sources were decomposed into extended and compact components. The radio source J0527+0331, identified with a BL Lac object, displays significant variations of time scales from several days to several years. Data on flux variations are presented for 11 radio sources, as well as their spectra at several epochs.     

New data on Upper Kimmeridgian-Tithonian biostratigraphy and ammonites of the eastern Crimea

Based on ammonites, Upper Kimmeridgian sediments are first established in the Crimean Mountains. The Kimmeridgian-Tithonian boundary recognizable in a continuous section is placed inside the Dvuyakomaya Formation of uniform largely clayey sediments. Assemblages of Kimmeridgian ammonites Lingulaticeras cf. procurvum (Ziegler), Pseudowaagenia gemmellariana Oloriz, Euvirgalithacoceras cf. tantalus (Herbich), Subplanites sp.) and Tithonian forms (?Lingulaticeras efimovi (Rogov), Phylloceras consaguineum Gemmellaro, Oloriziceras cf. schneidi Tavera, and Paraulacosphinctes cf. transitorius (Oppel) are described. A new biostratigraphic scheme proposed for the upper Tithonian-Berriasian of the Crimean Mountains includes the following new biostratigraphic units: the Euvirgalithacoceras cf. tantalus Beds of the upper Kimmeridgian, ?Lingulaticeras efimovi Beds of the lower Tithonian, and Oloriziceras cf. schneidi and Paraulacosphinctes cf. transitorius beds of the upper Tithonian. The middle Tithonian is proposed to consist of the fallauxi and semiforme (presumably) zones. The ammonities found determine the early Kimmeridgian-Berriasian age of the Dvuyakornaya Formation that is most likely in tectonic contact with the underlying Khutoran Formation.     

Computer microtomography of zircon: A new approach to the selection of targets for U-Pb geochronologic studies

The paper reports results obtained by the complex studying of zircon crystals from rocks of various genesis. Zircon is one of the minerals most often used as geochronometers. It also provides genetic information on superimposed processes that is “recorded” in the external and internal morphology of its crystals. This mineral is thoroughly examined to select its unaltered crystals for U-Pb dating by the single-grain method. Zircon grains are selected with the use of optical and electron microscopy and cathodoluminescence. This publication presents the first results obtained by examining zircon by computer microtomography (μCT) and the results of the studying of the external and internal structure by conventional techniques ([optical microscopy and SEM (SE and CL)]. The paper demonstrates the advantages of the application of the μCT techniques to the selection of targets for U-Pb zircon dating: there is no need for the special preparation of the samples and no material is destructed. However, this technique may be not informative enough if the zircon contains inherited core whose density does not differ from the density of the surrounding mineral.     

Hydrothermal sulfide deposits of the Lucky Strike vent field, Mid-Atlantic Ridge

Several hydrothermal sulfide structures were sampled using Mir manned submersibles in the relatively shallow Lucky Strike vent field, Mid-Atlantic Ridge; the bathymetric position of these structures varies by approximately 100 m. The investigation of the chemical and mineral compositions of hydrothermal ore occurrences led to the conclusion that the initial high-temperature ore-bearing solution ascending toward the surface became unstable and experienced phase separation beneath the ocean floor. The phase separation was responsible for the bathymetric control of hydrothermal ore formation in the ocean.